In a medium saucepan or microwave-safe bowl, melt the butter until just melted.
½ (113g) cup unsalted butter
Add the semi-sweet chocolate chips and cocoa powder to the melted butter. Whisk over low heat, or microwave in short bursts, until the chocolate has just melted and the mixture is smooth.
½ (120g) cup semi-sweet chocolate chips, ½ (42g) cup unsweetened cocoa powder
Transfer from heat as soon as the chocolate has melted if you used a pot, then pour the mixture into a mixing bowl.
Whisk in the granulated sugar, brown sugar, sourdough discard, eggs, and vanilla extract until the brownie batter is shiny and smooth.
1½ (300g) cups granulated white sugar, ¼ (50g) cup light brown sugar, ½ (120g) cup sourdough discard, 3 large eggs, 1 teaspoon vanilla extract
Add the flour, cornstarch, and salt to the brownie batter, and mix just until no streaks remain. Try not to overmix at this point or the brownies will be tough. You just want the flour incorporated.
2 teaspoons cornstarch, 1 (125g) cup all-purpose flour, 1½ teaspoons fine sea salt
Sourdough Discard Swap Option: If you don't have sourdough discard, add the extra flour and milk at this time and mix it into the brownie batter.
Spread the brownie batter over the graham cracker crust, making sure it reaches the edges. Smooth the top with a spatula.
Overnight Fermentation Option: If you want to ferment this brownie batter, cover with plastic and refrigerate overnight in the pan. When you're ready to bake your brownie, allow to rest at room temperature for about an hour to warm up then bake as instructed.
Transfer the brownies to the hot oven, and bake at 350°F for 35-40 minutes, or until the edges are set, the center no longer jiggles, and a toothpick inserted in the center comes out with moist fudgy crumbs.
Do not bake until the toothpick comes out completely clean. These brownies are meant to be fudgy and will continue to set as they cool. Baking time my vary on your oven, my brownies are done anywhere between 35-40 minutes.
Cool the brownies for at least 20 minutes or up to 24 hours before adding the marshmallows.