Preheat the oven to 325°F. Line a 9×13-inch baking pan with parchment, leaving overhang. Don't skip this step, it'll make removing the bars so much easier.
In a microwave safe bowl or a small pot, melt your butter and whisk until smooth. Transfer to your mixing bowl.
10 (140g) tbsp unsalted butter
Next add the brown sugar and white sugar to the butter, whisking to melt them together until the mixture is glossy.
¾ (150g) cup brown sugar, ¼ (50g) cup granulated sugar
Add the eggs, egg yolk, sourdough discard, vanilla, lemon zest, and lemon extract to the bowl and whisk until smooth.
2 large eggs, 1 egg yolk, ⅓ (80g) cup sourdough discard, 1 tsp vanilla extract, 1 tsp lemon extract, 2 tsp lemon zest
Measure your flour, baking powder, cornstarch, and salt into the wet ingredients, and combine until the dry ingredients are just mixed in and streaks don't remain. Don't overmix at this stage, or the bars will be tough.
1½ (180g) cups all-purpose flour, ¾ tsp baking powder, 2 tsp cornstarch, ½ tsp salt
Fold in the blueberries and white chocolate into the blondie batter gently, then spread the batter into the prepared pan evenly.
1 (120g) cup blueberries, 1 (150g) cup white chocolate chips
Optional Overnight Fermentation: if you want to let this batter rest to have the sourdough discard work it's magic, cover the blondie in the pan with plastic and transfer to the refrigerator overnight and bake the next day.
Bake the bar for 26-28 minutes, the edges should be browning and the center matte not shiny. You don't want to overbake these or the centers will be dry! Internal temperature of the center when done should be 195 F.
Remove the pan from the oven as soon as the bar is done, and allow to cool completely before proceeding with frosting the bars.